Description
1/29/16
Functional Groups and Nomenclature
alkane -Ç-©- or 1-Ç-H bosbe
only C+H and only single bonds and not to plantes
Hon cionof newing ot base alkene c = 6 (Ho) Carbonyl - c
alkyne -C=C
baldehyde -c- C-H
c =Ć.
Ly Ketone
-c- c-colas
A arene ti-C
u carboxylic acid
-¢-C-0-H) -
v
bester 3-6-6-0-¢-
Thalide -c-X
Don't forget about the age old question of What is distance formula and what are its examples?
X = F, Cl, Br, I
bamide
-c-C-N-rol
bacid chloride
-c-ci-cir
alcohol ether
-¢-O-H -c-o-c
sacid anhydride -¢-C-0-8-¢
amine -C-N-H I noor met zo zout bo imine -c-c-6-othandelt Hann ei-Ç-Ņ-
Hamad artib bomo
t
epoxide
-¢- Çarsani kot
de le Don't forget about the age old question of Why are discouraged workers not included in the unemployment rate?
phenol
-
Co-
H
annoo
-C-
N nitrile -C-CEN
nitro Sulfide -¢-s-c thiol -c-s-H
-C-s-
c
aniline
+ Hydrocarbons - Compounds containing only Carbon and Hydrogen
• Alkanes - Hydrocarbons made using only single bondsco Straight chain n-alkanes are homologs of the series H-(CH2)n-H, We also discuss several other topics like What are the two ways to exploit mass media?
and their molecular formula is CnH2n+2 ore
ext-8-8 - E-H is H-CCH2);-H -> C3H2.342 -> GHz
-CH3
The Normal Alkanes -C=1. Methane CH4 -C=2 Ethane C2H6 -=3 Propane & C3 Hs. -C=4 Butane Culho - C= 5 Pentane Cs Hotebog - C= 6 Hexane Chiu a + C = 7 Heptane & G His -C 8 Octane CGH18 -C=9 Nonane Cq H2o hi -C= 10 Decane Crotzz -C = 11 Undecane GHzy bow -C=12 Dodecane Ciz Hz We also discuss several other topics like White republicans southerners are called?
+ Isomers - Have the same number and types of atoms, but are
arranged differently. This cives isomers different physical and loc
Chemical properties from eachother Constitutional Isomers- Isomers that are different because of the
ways they are connected Also, constitutional Isomers of Pentane pentune" sn-pentane isopentane neopentane
Stud SOU
CH3CH2CH2CH2 CH3
CH CH CH2 CH3
CH3 Ihre CH3 C CH3 Don't forget about the age old question of What is the difference between society and culture?
will
"iso" Structural unit ibi "neo Structurat unit We also discuss several other topics like What did aristotle believe about the heart?
- CH2 D-
CHE
X CH3 CH3
CH3 CH3
.
CH3
-Alkyl - Formed when one Hydrogen is removed from an alkane
CH3
CHECHz
CH methyl
ethyl
isopropylen
CH3
Classifying sps Carbon atom type by C-C connectivity in - How many other Carbons is it connected to sendbor -Primary Carbon (10) - Bonded to I other Carbon l o cale -Secondary Carbon (20) - Bonded to 2 other Carbons estamox -Tertiary Carbon (3) - Bonded to 3 other Carbons en -Quaternary Carbon (4) Bonded to 4 other Carbons
Heņembantu R adio Roa ceneric H-C-H .R-ċ-H R-C-
R R -C-R saint alkyl group
I
an 2 -
3
de 4
a monta
Classifying Halides (-5, -C1, -Br, -I) and alcohols (-OH) by CC Connectivity
in
HW HURA 2 a 2
R-C-x R-C-X R-Ć-> -
Hlina Ropa y Ři Halide (X=-F, -Cl, Br, -I) a lo halide 2 halide 3 halide Alcohol (X=-OH)
l' alcohol 2° alcohol i 3 alcohol
Naming Butyl Compounds de ma bho shootout n-butyl alcohol isobutyl alcohol sec-butyl chloride tert-butyl bromide
(i-butyl alcohol) (s- butyl chloride) (t-butyl bromide)
HO-CH2CH2CH2Clty
HO-CH2
CA3
B
r
CH2
Naming the Hydrogen atom by it's CC connectivity
- RO H-6-H CH -C-
H A 3° hydrocen is allached to a
R osca 30 carbon, etc. Phydrogen 2 hydrogen
Determininke sp3 Carbon atom-type based on C-H connectivity
X and R are H-C-
H H -Ċ-H. H.-C-
X H -C-x interchangeable
methane
methyl
methylene
methine
of with
Examples:
H? R-C-
x
bos nine
mmatico
? H-CFH
Lo Carbon (ble IR group) Methyl (blc 3 hydrogens)
aka#ofC's .
it's connected
L
2° Carbon (based on#Rgroups)
ethine (based on #hydrogens)
De
m
Determining sps nitrogen atom type by C-N connectivity - 1 , 2 , 3 + 4 notation refers to the number of N-C bonds: for amines & amides
Amide: H-N-C-R
Are
R-N-C-B.
R-N-C-R
Amine
H-N-R
R-N-R
R-N-R
R-N-R
20 Polyester
,
3o
e 4o
"t" Charge: add "ium" suffix ' " charge add ide" suffix
RS Ex: R-N-R = quaternary ammonium
ion
Naminc Alkanes
C
9 Prefix + Parent The position what is the of the substituen's longest C-c
chain?
&
2/ 116 tourado ab Is Suffix odorato as teil hot 4 The functional i tate
group family
SEO
1. Find the longest Carbon Chain - The Parent -Name according to the number of carbons in the chain
GHz banat
oa ICH CH2 - CH - CH CH CH2 6 carbons = hept - heptane
G CH3
and also
- If there are two chains of equael length, choose the one with
more branches.
CH3-CH-CH2-CH3 ^ butane with 1 substituent
CH3 -CH=CH-CH2 butane with 2 substituents
-
- Stact numbering the carbons, Starting at the end closest to
the first branch point. antiboo bro CH3 m2 t anna hoond CH2 whitede sota
'C.H2 CH2 CH-CH-CH2 < - CH2 - CH CH CH 2 O
HH CH3 H4 H CH3 H7 1st branch on C# 3 X at 1st branch on C#2 V
- If the 1st branch point is the same number of carbons from
each end, begin numberinc from the end closer to the 2nd branch.
CH2
CH3 -CH="CH2 -CH=CH-CH3 CH2=CH-CH 2 -CH=CH-CHS.
CH3 m borboador to CH2 hon Gt3 cod 'CH3
CH3 1st branch @3
1st branch @3 A A 2nd breanen@s x
and branch @ 40
Std S
3. Identifier Substituents - Prefix - And list in alphabetical order for
2-methyl-> CH3 en CH3 <-5-methyl
CH3 CH3CH2CH2 CH-CH3
CH2 2-3-ethyl
CH2 - CH3 T
3-ethyl
2-methyl
5-methyl h e contban
4. Write out the name as one word.
· The Substituents are pot alphabetically in the prefix - "di", Fri",
"Sec" etc are not used to alphabetize butyl methyl etc are.
One exception : "iso"
• Hyphens separate prefixes about the youth and short T
Commas separate numbers
- If there is more than one of one kind of substituent, use di-tri-, etc 3-propyl CH2 - CH2 - CH3 i CH3 CH2 - CH2 -CH-CH2 - CH - CH2 - CH3
- 4-methyl CH3 CH2 4-3-methyl 3,4-dimethyl-5-propyloctane con att barnen toista
CH3
- 2-methyl
3-ethyl
5. If the Substituent is branched, name it seprately and add it in L CH3 CH2 CH3 CH2
I CH2 - CH2 - CH2 - CH3 -CH-CH-CH2-CH3 33-CH2 CH2 CH3 5-(1-methylpropyl) ♡ # CH-CH2 CH2 - CH2 1-methyl propyl (not - ane)
3-ethyl-2-methyl-5-11-methylpropyl) nonane
•Or, if you recoxnize the Structure (this is sec-butyl you can just d use that as the name : 5-sec-butyl - 3-ethyl-2-methyl nonane
• Aleways becin numberincs at the point of attachment of the branching 1 molecule.
Drop - one and add-yl for branched molecule.
3- Carbon Alkyl Group:
}}-Chus
s CH3 brod s
isopropyl
1 H les than alkane, but taken
from middle C
onde (H2 CH3 & CH CH3
14-Carbon Alkyl Groups:
Color CH2 codes
- -C- CH3
CH3 sec-butyl (sec-Bu) isobutyl (i-Bu) tert-butyl (t-Bu). H taken from 2nd C
It taken from tertiary C
3-CH2-CH CH3
&-CH2 CHC
CH.
CH3
5-Carbon Alkyl Groups:
на снимка на сн {}-CH2-CH2 - CH
& CH2-C-CH3 }} - ( - CH2 - CH3
CH3 ..CH3 isopentyl or isoamy! - neopentyl tert-pentyl or text-amyl
CH3