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UCONN - CHEM 2444 - Class Notes - Week 14

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UCONN - CHEM 2444 - Class Notes - Week 14

School: University of Connecticut
Department: Chemistry
Course: Organic Chemistry
Professor: Gregory Sotzing
Term: Spring 2017
Tags:
Name: Week14
Description: notes on remaining chapter 18 information
Uploaded: 04/27/2018
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School: University of Connecticut
Department: Chemistry
Course: Organic Chemistry
Professor: Gregory Sotzing
Term: Spring 2017
Tags:
Name: Week14
Description: notes on remaining chapter 18 information
Uploaded: 04/27/2018
2 Pages 14 Views 11 Unlocks
  • Better Grades Guarantee
  • 24/7 Homework help
  • Notes, Study Guides, Flashcards + More!

Unformatted text preview: CHO N A NO2 FEB 04|23 18 Ancak onio . CHUO AU Boaz opisut 9- a rector p-Chloco Noenzoic acid m-chloro benzoic acid needs on CH3 step l CH3 tookdraad cozita clz step com cu tortino AlCl3 #2 Hzccoy di toctimo _002 HIT deactivaa - Mdir cor cI 6024 > mdir con Ciz AlCl3 AICI3 Cl2cl More reactions O Dozonion salts a N aine stel SP I, BET NOC cu) - IDH azonium HO (aso o curo F CUNO3)2 CENA H2O ALLA NOCI IZ Sandmeyer Rens H BFY04|23|18 Moe Reoef ons Brco DBA NONOS Ihsoy HNO3 Br IC Ntz NOZ NO2 BS2 - FeBr3 de PC Br . FeBr3 Functionalizing in Aramotic Systems O Diazonium salts >> x-CN, etc... 042518 2 Alkylations Ron @ 50zuki cxn = biaryl + Hegeant des oss B-Beds 2 H (boronic acid) ac alkyl bococate B R > acid, Vinglalkg Palo Lo + R-BLOHHOOL * 'coupling can cet bond ester bose neusse biaryl PACO), K-CO3.pose on this happens ofter dat a diff time from EAS to mechanism Par these pdo COH NaOH alkyl auprote cuprate * Br b). Cuprotes BE A lusOCE Halogenation elim. KotBu HotBu Bra hy - benzylic bromi nonion - radica 10td LLL halogenoten gilylic halogenota L T Br Soz OT+ -OH > LY por - halogenation plus are eliminatia substitofia ON EL ON O Redox benzee desn't H2Y o benzeme huarooente H2 > R/C CY but A asa para card. NOZ nitro H NYNHY. > C CZNH2Y AANTAL N#2 LED Paney Ni Fmedet Csapts are slowest EAS runs

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