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UTD - CHEM 2323 - Class Notes - Week 8

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UTD - CHEM 2323 - Class Notes - Week 8

School: University of Texas at Dallas
Department: Chemistry
Course: Introductory Organic Chemistry I
Term: Fall 2018
Tags: Organic Chemistry, SN1, SN2, E1, E2, Methylshifts, hydrideshifts, and Chemistry
Name: CHEM 2323 Chapter 6 notes
Description: These notes cover what will be on the second exam (Chapter 4,6 & 7).
Uploaded: 10/19/2018
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Join more than 18,000+ college students at University of Texas at Dallas who use StudySoup to get ahead
School: University of Texas at Dallas
Department: Chemistry
Course: Introductory Organic Chemistry I
Term: Fall 2018
Tags: Organic Chemistry, SN1, SN2, E1, E2, Methylshifts, hydrideshifts, and Chemistry
Name: CHEM 2323 Chapter 6 notes
Description: These notes cover what will be on the second exam (Chapter 4,6 & 7).
Uploaded: 10/19/2018
2 Pages 46 Views 36 Unlocks
  • Better Grades Guarantee
  • 24/7 Homework help
  • Notes, Study Guides, Flashcards + More!

Unformatted text preview: PFPPP Thursday, 4th of October 2018. Chapter Six The role for a stran wa Ist Order ryo. Datet (substante.] 1st step is rate determining up and the nudeoplile ja NOT londued in the rate determing step. The sate un S1 does not depend on the Opera nud 2.op ble or nucleoplale charact loviti , og strength. The pry factor concerning the rate of a Swirknis the starlality Dy the Carbocation fermed - Other factes in Swans22 * Leowing group ability CI will have better than f) nam (4) no celorence (94) Vinyt with remix carbation 3 wita presencontr 3 no resonance Break Carbon- halogen bond Maite resonance Chot stb) Same as A ENT GC This should be bas bermalse Oxygen well pull electron density from the election definient Carbon Bu T t can reso norte So it will stabilize, which is good.Solvent poloty In a Spl oxo you want a polar protic solvent to stabilize Solvent neith Anigher polomity increases the parte dla typical SNICKA metanol etter acetone > hexane Comparison with Sn2 penn * Sulis NOT Stino Spectic due to planor intermediate so I can seteck at any where You octien obtein a racemic mixture in a Sul reaction La mixture that contains egen mount of right Ist handed enantiomer Of.a ebrioni moleculea Example 1 Br E+ # metusExample 2 Be hydride shipt - hydiy 30 # Lmore stable Carbocation Called rolerangements There is no need for methyl siit the stability of the Original molecule ends up being the Same with tat-o the new molecule. Cle 2 2 99. You can do a hydodde sinjt inst enda B => 3 67041

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