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MU - CHM 242 - Class Notes - Week 1

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School: Miami University
Department: Chemistry
Course: Organic Chemistry 2
Professor: Richard Taylor
Term: Spring 2019
Tags: Organic Chemistry
Name: CHM 242 Week 1 and 2 Notes
Description: dienes, Diels Alder, aromaticity
Uploaded: 01/29/2019
4 Pages 21 Views 16 Unlocks
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School: Miami University
Department: Chemistry
Course: Organic Chemistry 2
Professor: Richard Taylor
Term: Spring 2019
Tags: Organic Chemistry
Name: CHM 242 Week 1 and 2 Notes
Description: dienes, Diels Alder, aromaticity
Uploaded: 01/29/2019

Unformatted text preview: Study REPARED BY PROJECT TITLE: CH 16 Conjugated Pl Sustens. Dienes Dies-Alder Reochon Dienes: pi systems of two double bond's larca Olkene 1. cumulated: A bonds adiacent Stohle > 2. Conjugored pi bong sengiateo by exachy 1 Single bond 3. isolated pi bonds separated by > single bond pocbitos goly exist for Sp?ond so atoms Sot nas sne pobial Sp cas Two Hetercaton's may be lovclved in COMI6ATED susten NA coniugated dienes can be Pormed by, elmgration using Be bulka bose 2 Sigie bonds in conjuga rosyster ore SHORTER than normal single bonds - hibridization of caroon affects bond length - more S-character, shole bonds P503 Sp' 5PS 0% 25%. 337. 507 1007. ->5 character(Astu Stability 2 single bends rotate - S-CIS s-Frans 2-2 rost Stable cotonunal conformations for bulad ene simple con geted diene, are s-525 and S ons hots allow for full p suster ovedop molecules wlton ucorion are more stable than w conjugation, but iese stable than uniy single bar be | most shall last stable - hras more stable na seis due to Stenics List in order at ne Stucilit Bochice 8 Cis o ns Cs. Betop doition fenerber Morkouriko adoric of 4-X in ons CEC with note de 2 a 30 start. 10 pructs are possed cena Cou rhod shall Er to u s 2015 Sto 1: Pi 2-0 . we niet stable eToMA bocoVC KTO List and stable mt te placeres and in ved H i NCT FORMEDPREPARED BY: DATE PROJECT TITLE Step 2: od o'rocks regrance stated carbucation either sile storing the charge - number systey denives from the fact that starting diene has y C 0-3 orbatoa inang orbutin 1,2 und 1,4 boduct is Ten ERPTURE DEVEDIAT 1. duc Br 11.dict meer rett For U SODS . rece rca e ouds36 HENRI Cordom S rbon Il BRUNO metice Come pobocor is vol sta r , ?? PPT Para V.1.4 - The wo ton m ento o 'Seren imperatura berendy low to vos 12 porcu **204713 rearkion coutunate delt Trips Faster Tools for a sfolle because it mos mer substuted air o t is