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MU - CHM 242 - Class Notes - Week 5

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MU - CHM 242 - Class Notes - Week 5

School: Miami University
Department: Chemistry
Course: Organic Chemistry 2
Professor: Richard Taylor
Term: Spring 2019
Tags: Organic Chemistry
Name: CHM 242 week 5 notes
Description: end of chapter 18, starting ch 12
Uploaded: 03/03/2019
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Join more than 18,000+ college students at Miami University who use StudySoup to get ahead
School: Miami University
Department: Chemistry
Course: Organic Chemistry 2
Professor: Richard Taylor
Term: Spring 2019
Tags: Organic Chemistry
Name: CHM 242 week 5 notes
Description: end of chapter 18, starting ch 12
Uploaded: 03/03/2019
2 Pages 14 Views 11 Unlocks
  • Better Grades Guarantee
  • 24/7 Homework help
  • Notes, Study Guides, Flashcards + More!

Unformatted text preview: PREPARED BY: PROJECT THE Nucleophilic Aromatic Subst uman (NAS) enerally como nino Sare electron rich an undergoest EAS 10 Puhh attack an cctrophile under raht Conditions, it is also possole to have nuoleophic. gramatic Bubshiruna INSS) which Borghi e ring, arching tracked by nucicoprile OPRES coleria Must be met for an NAS reachin te ocur -Ting must contain powerful electron withdrawing group iuually phoroup! cing must corrain le group usuarly. cr halde) -heating group must be either other para withdrawing group electron sr 04 hydroxide, cold ruleophile TOP: ocks banene ring und group NIZ - Un cachon huches 3 stap TOPS voleopholdt attack followed by 12Vgg Up resonance shabere intermediate s complex rete na native charte alle de Meisenheimer - sis in Den Tost to the sio ma complex coserved in an LAS feaction which has post change Loss of OH leaving Meisenheimer Caroplex group wires Sr. Bechon wthorquing Group NAS react'ch? W is this group b portant for en -Mro Oloup startes melewaleht benet eleurch onheur Paco baidim neacce charge och in bu nurkaphiken ervoir -ntru grupumus?- 130 bz ortho or paid so it can por in france into cup was meta we not be able to attacker parte diluze negative chaneElimination - Addison Reactions wlo elechon witharawing group00 reaction crcuns however, @nigh temp. reachon occurs, tout does not follows some tegibehemical outcome oS NAS reachon alt. Allt 2) H30 NOD reactor Macit, 3SC C Az these eachons follow completely ditierent pathway than NFS reaution and that it had completely dit inemedisiebene 1. hydroxide functions as base f-deproteriales primene me 2. leaving group is exted, generang benzyne intermediate 3, mudroxide functions as muceophile tattacks bencana 4. resultma arin removes into trom water towed out Proton frunte +1oss of leaving oruupielimano ya ben wyne Benzere 409 Niple oond that itacked the glue addition product tiple bond of benes no a true iple bond rewall Heatin e ple and carbons are so he ordized W/180 degree bond angles . Instead, it is ne per descobed of diradical EAS Ditentum Mechanism of Aromaht Bubshhon Beactica 2 elechapelle renons sech Gplus of hilophilic SAAB Tutuphic ished for NAS yes e all sheria FremPROJECT TITLE Chapter 12 Alcohols and Phenols OH group while phenols possess Althois possess hydro Stop Cronol opend Uphenol Nomenclature Alichos keres e homens same produce procedure to wome 2Idenhly parent cham, which should include carbon that OH aHathed to 2. Ilenhiu tame substituents 3. Assign locant it profie) to each substituen? Gue carbon atached HOBH the lowestral hy precedence over C=C double bonds 4. List od substituents belore parent name in alphabehar order tomore memes S cudo on iso 5. OH locount laced before parent come or beture cl suffix - Short RSS configurations bed of some porno let hols ue based on HOT!, SG GFS 914 s. 3- penional or --chloro-3-phenyi- proc ! Womensluhure - Acehchs Prenos eges olchals are d by 0 o di uur theula Secondary terjany when -014 is whachad he sentene me parent nom s L e 4 chloro-7 hitrophenol

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