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Physical Chemistry I

by: Patrick Schmeler

Physical Chemistry I CHEM 3410

Marketplace > University of Virginia > Chemistry > CHEM 3410 > Physical Chemistry I
Patrick Schmeler
GPA 3.55

Frederick Richardson

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Frederick Richardson
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This 1 page Study Guide was uploaded by Patrick Schmeler on Monday September 21, 2015. The Study Guide belongs to CHEM 3410 at University of Virginia taught by Frederick Richardson in Fall. Since its upload, it has received 43 views. For similar materials see /class/209791/chem-3410-university-of-virginia in Chemistry at University of Virginia.


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Date Created: 09/21/15
Key Concepts for Final First Order Reactions A Ala 6 t12 2 k relaxation time 139 Plot of In At or In L vs time yields a straight line of slope k for a firstorder reaction AL Second Order Reactions 1 1 Al Al I 12 HAL 1 Plot of W vs t1me g1ves a straight lme of slope k for a secondorder reactlon I Simple Arrhenius Analysis k AeiEaRT where A is the preexponential factor Ea is the Arrhenius activation energy Plot of In k vs 1 T are Arrhenius plots of rateconstant data and they yield values for Em and A according to E slope id intercept In A Modi ed Arrhenius Analysis k A39TmeiEVRT k AITmemeiEaRT where Arrhenius preeXponential factor A A39Tmem Eyring Analysis k VKe AGuansmon stateRT Ink 1n klK AStransition state A Itransition state T h R RT We know from the above equation that from a plot of In k T vs 1 T we can nd the following


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