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Organic Chemistry Study Guide Exam 2

by: Elizabeth Zeccola

Organic Chemistry Study Guide Exam 2 CHEM 2250

Marketplace > Rensselaer Polytechnic Institute > Chemistry > CHEM 2250 > Organic Chemistry Study Guide Exam 2
Elizabeth Zeccola
GPA 3.2
Organic Chemistry 1
Lisa Morkowchuk

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About this Document

A brief study guide for exam 2
Organic Chemistry 1
Lisa Morkowchuk
Study Guide
50 ?




Popular in Organic Chemistry 1

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This 10 page Study Guide was uploaded by Elizabeth Zeccola on Tuesday October 27, 2015. The Study Guide belongs to CHEM 2250 at Rensselaer Polytechnic Institute taught by Lisa Morkowchuk in Summer 2015. Since its upload, it has received 38 views. For similar materials see Organic Chemistry 1 in Chemistry at Rensselaer Polytechnic Institute.


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Date Created: 10/27/15
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enamiomerio excess f behavior of racemic mixtures 2 CHAPTER FIVE idogroe of unsat39umtion a l 2 1 1 if H Vi l fnomenclaturo of alkenes common and IUPAC 5125 Clotrans 4EZ quot 3 I mlcleophiles and olectrophilos M the characteri tic reaction of alkenes electrophilic addition of 3 transition st ates 9 0 reaction coordinate diagrams 7 o catalysts and their effects on reestion speed a a thermodynamics 5 for mA nB 80 tD Keg l A Gibbs energy AGO E G Gigacmms m RT In Km 2 1511 O TASO Products om exergonio vs endergonie reactions elm exothermic vs endothermic reactions Vwr o39o o ff enth ilp ampH m Hproducts reactants entropy A50 freedom of motion chaos randomness 5quot S metimes AGD can be approximated by AHO H u The rose en39ssow oil quot3 rm cm 316 kinetics v 39 L 4quot Sr39l al hli k39 VF e a maimed 9 0 amp segdrook 12 4 the rim Gibbs free energy AG Grs m Greoetonts 2 AH TASI x a ways POSitiVe webihk Vii infw kinetic vs thermodynamic stability r L I i K z 7 r Emotieel 0 AG quotl 5quot Pl39f 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i a x I 19 relative S tabilities of oarbocations 33 regioselectivity clue to hyperoonjugation in the intermediates L the Hammond Postuloto T 31 Q Markovnilcov s Rule in carbocation i earrangomento Ailt 12 hydride Shifts 5 12 methyl Shifts stereosoleotivity of reactions due to 5an anti limitations or sterio e octs 5 a alkene reactions with m H2 on PolC m H20 acid oatalyst m alcohols acid catalyst BHgTHF or BREETHE then O mHgOEQOQ Clg or Brg 3121120 or BigL120 peroxyacids m ozone then CH3QS or ZnC gCOCH a nomonclature of opoxidos a concerted moohanismo 5 CHAPTER SEVEN a structure of alkynos a physical preparties of alkynes 9 nomenclature of alky es o nomenclature of alkenes with a second functional group 0 formation of internal alkynos from terminal alkynos reaction of alkynos with HX regiooeleotiviiy probaljlo intermediate based on anti addition continuation to an alkane reactions 0f asymmetrical internal alkynes with EX at regioseiective ampdciiti0n of Bfg 0 C12 to an aikyne addition 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