Organic chemistry 4
Organic chemistry 4 CHEM 2535
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This 4 page Class Notes was uploaded by Savah Notetaker on Friday September 23, 2016. The Class Notes belongs to CHEM 2535 at Virginia Polytechnic Institute and State University taught by Jatinder Josan in Summer 2016. Since its upload, it has received 7 views. For similar materials see Organic Chemistry in Chemistry at Virginia Polytechnic Institute and State University.
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Date Created: 09/23/16
Organic Chemistry Equilibrium constant eA + fB sC + tD K eq[C] [D] / [A] [B] f Thermodynamics Y Z Thermodynamics: how much of ‘Z’ is formed Kinetics: How fast ‘Z’ is formed ∆G⁰ =RTln K eq logK eq pka (conjugate acid) pka (acid) ∆G⁰ = ∆H⁰ – T ∆S⁰ Bond dissociation Energy (BDE) = BDE (bonds broken) – BDE (bonds formed) HH + CH – C3 CH CH 2 CH – C3 2 H H Rate = frequency of collision X fraction of proper orientation X fraction with sufficient (How fast) (location) (energy) Rate determining step of reaction A to reaction G
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