week 5 notes
week 5 notes Chem 2400
Popular in Organic Chemistry 1
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This 3 page Class Notes was uploaded by Brooke Martin on Sunday October 2, 2016. The Class Notes belongs to Chem 2400 at Georgia State University taught by Reber in Fall 2017. Since its upload, it has received 17 views. For similar materials see Organic Chemistry 1 in Chemistry at Georgia State University.
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Date Created: 10/02/16
Organic Chemistry MWF 12:00 PM Week 6 Notes September 30, 2016 CHAIR CONFORMATION Cyclohexane Strain free 3D All C-C bond angels are 109⁰ tetrahedral All C-H bonds are staggered Lower bond is front and upper bond is back BOAT CONFORMATION No angel strain Eclipsing interactions Less stable than chain conformation TWIST BOAT CONFORMATION o Nearly free of angel strain o Steric and torsional strain AXIAL AND EQUITORIAL Axial – perpendicular to ring axis Equatorial – rough plane around ring Each carbon has one axial and one equatorial H The face of the ring has three axial and equatorial hydrogens Equatorial substituents are more stable than axial 1,3 diaxial interactions – energy difference between axial and equatorial due to steric strain Example
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