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by: Michael Reilly


Michael Reilly
GPA 3.71


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Class Notes
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This 2 page Class Notes was uploaded by Michael Reilly on Friday September 4, 2015. The Class Notes belongs to CHEM 0014B at University of California - Los Angeles taught by Staff in Fall. Since its upload, it has received 39 views. For similar materials see /class/177984/chem-0014b-university-of-california-los-angeles in Chemistry at University of California - Los Angeles.




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Date Created: 09/04/15
Weekly Lecture Schedule CHEM 14B Instructor Dr Laurence Lavelle WINTER 2005 WEEKS 7 amp 8 Functional Groups Alkanes amp Cycloalkanes Alkenes Read Bruice Ch 2 Do Problems 1 4 6 7 8 9 10 12 14 17 18 26 27 30 35 36 38 Read Bruice Ch 31 to end of 35 See your Chem 14A notes for review of 33 and 34 Do Problems 3 5 6 7 9 10 Review of molecular structure and bonding from Chem 14A Bruice Ch 11 to end of 116 Lewis structures formal charges resonance VSEPR model hybrid orbitals sp sp2 sp3 and their geometry39s molecular orbitals electronegativity dipole moments polarity After going through the readings amp problems and attending the lectures amp discussion groups you should be able to Identify and name functional groups Identify primary secondary tertiary and quaternary carbons hydrogens and nitrogens Identify and draw alkanes cycloalkanes and alkenes Give IUPAC and common names for alkanes cycloalkanes and alkenes Identify constitutional isomers Distinguish and name alkanes alkenes alkynes Recognize and name haloalkanes haloalkenes alcohols ethers aldehydes ketones carboxylic acids amines given a molecular structure Know the cis trans and E Z naming system for geometric isomers Draw and interpret two and threedimensional representations of molecules and describe the structural information each reveals Use ChemDraw and Chem3D to build manipulate and energy minimize molecular structures Draw Newman structures and visualize molecules from Newman structures Understand and give examples or identify the different terms used to describe molecular conformations dihedral angles staggered eclipsed gauche anti Understand graphs of potential energy vs dihedral angle and why the potential energy depends on dihedral angles Understand the terms torsional strain and steric strain and be able to identify strained conformations See pages 2 and 3 WEEKS 7 amp 8 CONTINUED Calculate the ratio oftwo conformations given their relative energy AG RT ln Keq Describe the conformations of cyclopropane cyclobutane cyclopentane cyclohexane and their relative stabilities o Relate the degree of strain to the size of a ring 0 Identify axial and equatorial substituents o Visualize and draw the chair and boat conformations of cyclohexane and identify significant nonbonded interactions 0 Identify and draw cis trans isomers in substituted cyclohexanes and determine their relative stabilities For additional organic material go to your organic text web site at httpcwxprenhallcombookbindpubbooksbruice2 Visit this site when you want to gain a richer perspective and a deeper understanding of the concepts and issues discussed in Organic Chemistry This site is enhanced with Practice exercises with detailed speci c links amp feedback that can be instantly graded A gallery of 3D molecules to help visualize organic molecules Online quizzes which include instant scoring and coaching Online molecule gallery which includes useful tools for exploring organic chemistry ChemOf ce activities appropriate for each chapter


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