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Organic Chem Health Sci

by: Mr. Cornell Weimann

Organic Chem Health Sci CHE 118C

Mr. Cornell Weimann
GPA 3.76

Melekeh Nasiri

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About this Document

Melekeh Nasiri
Class Notes
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This 1 page Class Notes was uploaded by Mr. Cornell Weimann on Wednesday September 9, 2015. The Class Notes belongs to CHE 118C at University of California - Davis taught by Melekeh Nasiri in Fall. Since its upload, it has received 83 views. For similar materials see /class/191939/che-118c-university-of-california-davis in Chemistry at University of California - Davis.

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Date Created: 09/09/15
Mechanism of Edman Degradation for N Terminal Analysis of Peptides S O NH Peptide O 9 ICIA C C6H5 y N H mi Hz CTR R C6H5 H s C Phenyl isothiocyanate C H Proton NH Peptide shift 3 C6H5NCQQH C6HS N C N H H 11 S C R S C H C H eOC NHPeptide H0 NH Peptlde C6H5yC N H R C H IIC N H s CH 6 5 R e C gt PeptldeNH2 s CltH H3O 0 O C 03N Peptlde H20 H H O Thiazolinone H20 C6H5 eN C N H C6H5NCNH C6H5 NC N H quot Proton CR R R hift s C S H S CH gt C H C II gt Ho HO 0 H20 0 H H90 H H IiI Ring opening C6H5NCN H C6H5 9 OH NH C S CHR same as I I C S CNC R H 0 OH H 5 C H 0 C6H5 IFIH OH Ring closure 6 5 III 0 gt S CNC R formation of amide S CNCR I H I H H H Phenylthiohydantoin derived from amino acid


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