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by: Carmela Kilback


Carmela Kilback
GPA 3.92

Niels Andersen

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About this Document

Niels Andersen
Class Notes
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This 1 page Class Notes was uploaded by Carmela Kilback on Wednesday September 9, 2015. The Class Notes belongs to CHEM 530 at University of Washington taught by Niels Andersen in Fall. Since its upload, it has received 28 views. For similar materials see /class/192552/chem-530-university-of-washington in Chemistry at University of Washington.




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Date Created: 09/09/15
Outline of Material Covered Weeks 5 8 Next test will be November 28 or 30 Chap 5 Reactive Intermediates Radicals 257 262265 272 274 275 279 carbenes carbocations 283 294 through Fig 546 carbanions 302310 Chap 6 Additional material on substituent effect pO39 correlations 366377 Solvent effects also p 490 492and application of kinetics for de ning mechanism 329349 also aromatic substitution 380 1 453 456 513 21 in Chap 8 Chap 7 AcidBase Behavior and Catalysis 394 403 40311 gas phase and other acidities mostly from lecture as DMSO vs gas phase acidities acidity functions 411 416 AcidBaseCatalysis 416444 416 421 4215 426 9 434 443ester hydrolysis Chap 8 Nucleophilicity and Nucleophilic Substitution 455 7 505 including Table 815 You may skip the ANDN description of mech 4556 particularly important sections 456 64 467 470 amp 498 500 nucleophilicity scales 478 484 anchimeric assistance 4958 substrate effects in SN2 reactions more Suggested Problems by chapter from Carroll text Chapter 5 6 9 13 Chapter 7 2 4 7 rationalize more completely 14 16 22 Chapter 8 1 2 3 5 6 7 10 14b Carey and Sundberg practice problems Chap 5 Nucleophilic Substitution pp 257295 sec 59 510 511 to p 316 practice problems 1 2bg 3abceg 7 8 15d 20ab


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