Survey of Organic Chemistry
Survey of Organic Chemistry CEM 143
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This 3 page Class Notes was uploaded by Ladarius Rohan on Saturday September 19, 2015. The Class Notes belongs to CEM 143 at Michigan State University taught by Chrysoula Vasileiou in Fall. Since its upload, it has received 16 views. For similar materials see /class/207682/cem-143-michigan-state-university in Chemistry at Michigan State University.
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Date Created: 09/19/15
CEM 143 SS 2013 Common Names 39239 of Carbon amp Naming 1 C 9 meth 2 C 9 eth 3 C 9 prop 4 C 9 but 5 C 9 pent 39239 Substituent I no 0 ML methyl Me ethyl Et propyl nPr isopropyl i Pr butyl nBu secbutyl isobutyl i Bu tertbutyl tBu i rgg YuLing Lien 6C9heX 7C9hept 8C90ct 9C9n0n 10C9dec DA phenyl Ph m benzyl an A vi nyl N allyl O formyl H O J acetyl 0 gt29 be nzoyl CEM 143 SS 2013 YuLing Lien Ch6 Handout 39239 Carbon Cation Stability i gt Ft Ft Ft Ft H H 9 H 3 2 1 methyl Ft H H Jagtlt gtJ Ft 39239 Substitution Reactions For 1 and 2 Alkyl Halides SN2 m39Na r gt KCgt H 9 OH N CI A transition state a r H 0 transition state inverted stereochemistry Note After SNZ the chirality is inverted For 3 Alkyl Halides 8N1 or a iop intermediate 9A 9H Br NaOH OH r p a M g 9 intermediate CEM 143 SS 2013 YuLing Lien Ch8 Handout 39239 Preparation of Ethers V From Alkenes OH M Arov V Williamson Ether Synthesis Note displacement of halides amp SN2 reactions A A N H MCIH 0 Br O 2 39239 Reactions of Ethers Acidic Cleavage 00 HI OOH gt Note products will be less substituted halide and more substituted alcohol 39239 Preparation of Epoxides mCPBA o OrOH gt A mCPBA CI 39239 Reactions of Epoxides V Epoxide Ring Opening Acidic condition CAP 3 9 CHGOH O a H gt A C OH OH OH L o gt O A W VOH Note Carbon cation stability is 3 gt 2 gt 1
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