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Introduction To Chemistry II

by: Austen Pollich

Introduction To Chemistry II CHM 12600

Marketplace > Purdue University > Chemistry > CHM 12600 > Introduction To Chemistry II
Austen Pollich
GPA 3.75

John Nash

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John Nash
Class Notes
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This 1 page Class Notes was uploaded by Austen Pollich on Saturday September 19, 2015. The Class Notes belongs to CHM 12600 at Purdue University taught by John Nash in Fall. Since its upload, it has received 40 views. For similar materials see /class/207967/chm-12600-purdue-university in Chemistry at Purdue University.


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Date Created: 09/19/15
Electron Configurations for Neutral Transition Metal Atoms Ar 1s2 2s2 2p6 3s2 3p6 neutral atom electron SC 4s Ti 4s V 4s Cr 4s Mn 45 Fe 4s C0 4s 3d Ni 4s Cu 4s Z11 4s aThe 4s and 3d orbitals are very nearly degenerate electronelectron repulsion is minimized by placing one electron in each orbital bThe energies of the 3d orbitals are slightly less than the energy of the 4s orbital lling the 3d subshell provides a more energetically favorable con guration Electron Configurations for Positive Transition Metal Ions 0 the energies of the 3d orbitals are signi cantly lower than the energy of the 4s orbital 0 electron con gurations usually written by lling in the electrons from the bottom ie ls2 2s2 2p6 etc electron con gurations for positive transition metal ions can be derived by removing electrons from the top of the neutral transition metal atom Le remove as many electrons as needed starting with the 4s electrons Examples OLE CL Co Ar 4s2 3d7 Co Ar 4s2 3d7 Co Ar 3d7 003 Ar 3d6


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