Survey of Chemistry II
Survey of Chemistry II CHEM 1152K
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This 9 page Class Notes was uploaded by Jeff Gleichner on Tuesday October 27, 2015. The Class Notes belongs to CHEM 1152K at University of West Georgia taught by Staff in Fall. Since its upload, it has received 24 views. For similar materials see /class/230256/chem-1152k-university-of-west-georgia in Chemistry at University of West Georgia.
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Date Created: 10/27/15
Homework Draw the structure of each of the following a 33d methyI1pentene H55 0 5 J Han 0 3 H C C H an bond lulu orlvns 1 H hervgrn aquot 30 H b Draw the structure a an alkyne such as emyne acetylene and glve the value of all the band angles H C a c 39H N 5mg LLwvrr 0 n d 1 Maya 4 Mpdul39e 16 Ajlkenel39seAlkyn s 3 Draw cisZbutene and Its tmns lsDrner c C A 5 H I H quot1 C m c C i A zcl39H 394 C 4 Draw the structure of each of the follawlng Labei the structures to tell which is which a cisraAdlmethylzpentzne and nansBAdImethlZpentene EH5 ffm gt b cis4ethyI3 heptene and transiaiethyHheptene 39 W L m wh N JP and uMP39 cum1 quot 5quotquot C c rquot V Me a 39 If ff rZyyH m 4 LU39 4 v 39 EH3 follnwlng reactions and name the product Use nds I Wu 5 Write a chemlcal equation for each of the structure formulas for all arganl com nu a 13butadlene plus hydrogen Sample on p 456 or textbook quot Maud h uxmt quot J 1 g I C aw LHL gt H L M 1 4 m ens Hz viz 3 b cycluhexane plus chlorlne Sample on p 45s of textbook c ChiFla I 2 39 H C C H 739 cAJavledzblrranc l 4 1c quot CQHIIC39 H c L H 20 5 7 8 c propane plus hydragen bromide Sample on pr 459 of textbook H rkc Il 39H C x F quot539 CM5CHBrcH3 A l4 v C Ufa l cu u nern 2 kaP Vf Mlt d 2methylZebutene plus water Sample on p 461 of textbook HSC H 3 C C CH3 H34 Hr CRS CH C NI no gt de yl 5 an erte the general equatlan fur the hydrogenation of an alkene an fol ml Infernal a 4 H M4 5 LlKgquot WW2 allmc Write the genera equation for the halogenatlon of an alkene r c 39 C Fz 5 ywcec V v erte the general equauon for the hydrchalogenatlon of an alkene H 1 l I C C H 7lt e C lt I Write the general equauon for the hydratiun of an aikene no H H30 H 50739 e I a l C 0 Fr L l C a I 21 M dul l Alkanesilkrynes ID What is Markovnlkov39s rule To what types of reactlon does It apply whetHy 50m ath Roth cnsululp Pygsz m 35 me 1quot ocH hmh u svmmIn39m39lj SILKka all f ls H Wain H ALym Wm h rumC Ayo luy mg 11 what aces the term aromatlc mean m organ chemlstry What is the bask aramatlc campnund Osmium my a qu m r Madam and Aw PMS W FL 05 1 h 4 saw17d 40W A mu k LVNHJ39LV f4Ll z um m unjua Hm aim also ha vasmd may Emame 1c 4 12 lee an example equation to Illustrate each of the 3 types of substitutlon reactlons posslble on benzene Oxi al39m 2C Hut 3950 quot wa who r Wquot ode A u 3 60 c m 5 Cu 11 u wmg Fag cadahum mum My Ch r m a a use r HC Hm 07 Mar Hm VLquot It 701 H LI 6 U 10 51h w Homework From what you should have learned and remembered fmm CHEM 1151 de ne Lhe following L elcwomga viw M I M 5411 M mar L imcl my m 1 AW quot n quotow 311 39 1 Im lxlwnrl owl4 11 14 Lvylomc bond ll I w mumLHn Wm 3 covalentbond m WA a t all N I j quot 39 HWnu g izom gt v I 39 LA 11 hydrogen bond H 1 who I h V 1 v 1mm v 1 V a mic u quot rrra39h Also you should scratch your memory cells for what you can recall aboutpolarity f What makes a bond polar What makes a molecule polar MA ev tm in a n s in NA slalva tquot L A 3 F s0617 4148 hqu unfunny 9 M rs M 4 my M 4 mm w my mun obk lukd May Now let s start on something different 5 What do ALL organic compounds have in common 3 all Ann arhr 1 Hm I I 7 13 4 I A l LI39 n u u writethe a unshimdpnirs quot H I I H C c G H I I H H b The condensed structural formula for properre aka propylene is CHJCHCH2 Write the 39 39 r this molecule this time using dots for all valence electrons Are complete Lewis stru there any unshared pairs H H 1 no unshared Pot 1 5 C C H H 9 8 In a molecule where carbons have 4 dis not iaonds what is the geometry around the carbon alom igtra PM ha I angle formula for an alkane Give its name molecular formula and ex la Oriana M 9 Following is the line pmded structural formu C H 3 an 4 rig compounds 1 3bromo54recbutylnonane 10 Draw the structure of each of the followi a2meIhyl5isopropyloctane a aquot 6 a f39 Iquot f M r57 quot thequot dill 73772 57 u H441 H imam N M 4 Draw the lineangle structure base ormula If the two namestr Then write the molecular f tell w e e the tw es represent the same compound 23diethylpentane and 3eLhyl2methylhexane W il 39 W W W M Hl tmtiitl s b a sevenrmembered ring with a ferlbmyl gmup mlnched LEVI bufgl mph 14 mu L L isomedsm rlt L draw both isomers a l3dincd1ylcyclnpenlnne lt gt quotSC H5 H1 quot5 1 clhylcyclupamuy c 1memyl4pmpylcyclohcxane k L c L H5 m 1 LHIL 3 ti y lmquot 9 Homework 39 I U mumml mumquot undrmminm f a Latinng grown C 51ij 0 539 A 9quot 439 Su ma1 a I u Ye u L each of the classes of aluohuIs o lfo wuj1239 sardor qad B39de W i m 2 0 Elkane VQWJwI Z39W 11 H n 39 aquot as 5 4amp3 C H5 1 5 unreal ma Phinels a4 awr muff 5 I n NixieV161 gleam Aqal 7 f ltgtr n u 3 mwkr 2n mm Jada it ekwu aW y W C quot C 03quot 5pm mama who at H JV Ma y m AIL7 rav yI r uJ Emma ZRm 4 How does the structure of ether affect their physical properlics f ws 1lt AhabS 1 yumIns v FNMA MMquot 9L 4 A 41 4 nfm 57 aIzyV q 77 gr 5 2 quot Mr1 HATE 94 5 n1 205m dichromaxe 5 Alnu J ran39l 6e and251 Wkk Ahav3 w a JK g 44 395 r A M It whf basal 9quot 6255 7 29 w mmm wk 1 KL 4 rquot hm and 69410 mm 6 Explain u anuzub 39 mm m zach 39 mum man A equot 39 x f I M quotbquot MIMIquot WC M 0H 9mg Numb Mains rml ults J 1 MMI W llalmls wdh 52Mquot or l9 6 all e 10 smile Elm M m J H was MM m MIQvj wAxe 4w m7 7 l l l A m a Dehydration of an alcohol to give an alkene u on H I 1 quot o l u c 1 C c 1 b Dchydralion ofan alcohol to give an ether 4 l am w W mum Mo 3 41mm 9 TEST aw ui BMW mquot It M5 c Oxidauon ofpnmary alculmls Cartel o Mdthade mo anemia Mamie can C 03 o 155quot on A a I L C 41 a d Oxirlmion ofsccundary alcohols L Q quot IE 3K 0 R e Oxidation of lertimy alcohols krw i resmlonf 0 3 50 Vt 0 quot quot quot 539 R 8 Complete problem 1341 on ten page 500 alps alzalol a all any aWbub v m W RMJWi lS39Z P I tawdry Mum a I I 41quotquotan lanky 1 I u u HM OH 5 primal 5 55 quot 39j I Aer 3 So 930 o mug g frmwj 9 Camp pro lemlSAG on text page 501 4 0 r dz lens Wquot 1 513cm 5 sum n water bk 4 M ram u w mmdmw Meow Pam we DH 5 wt nu 45511 MU 11 nuL is nnpolpr mum and HmrsFquotquot 5quot L l i 5 lam are 5 5pm 10 bl 391 we 53358 wavy Au In fr enze a cyl3MW quot7 quot m a granfS all I H 39cu1ul5 10 Complele problem 1356 on texl page 502 K 39 Ch 47015 43511 0 5 Jimmy my blue City 5 quot P H 24C 770 30 H cu1cus