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Which of the two isomers in each of the following sets should have the greater basicity

Organic Chemistry | 6th Edition | ISBN: 9781936221349 | Authors: Marc Loudon, Jim Parise ISBN: 9781936221349 461

Solution for problem 21.9 Chapter 21.5

Organic Chemistry | 6th Edition

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Organic Chemistry | 6th Edition | ISBN: 9781936221349 | Authors: Marc Loudon, Jim Parise

Organic Chemistry | 6th Edition

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Problem 21.9

Which of the two isomers in each of the following sets should have the greater basicity at the carbonyl oxygen? Explain. (a) (b) (c)

Step-by-Step Solution:
Step 1 of 3

IonicCompounds Ion:transferofoneormoreelectronsfromonatomtoanotherandforelectricallycharged particles Atomsgainreadilygainorloseelectrons Achargedparticleiscalledanion Ionswithapositivecharge:Cation Ionswithanegativecharge:Anion Moleculeswithapositiveornegativecharge-Polyatomicions Ionsbehavedifferentlythantheirrespectiveatoms NawillbehavedifferentlythanNa + Typically,ionicbondsarebetweenametalandnon-metal Transferofelectronsbetweenspecies IonChargePrediction GeneralRules: 1. Metalstendtoloseelectrons(Cation) 2. Non-metalstendtogainelectrons(anion) 3. Thenumberofelectronatomslostisrelatedtoitspositionontheperiodictable 4. Atomsgain

Step 2 of 3

Chapter 21.5, Problem 21.9 is Solved
Step 3 of 3

Textbook: Organic Chemistry
Edition: 6
Author: Marc Loudon, Jim Parise
ISBN: 9781936221349

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Which of the two isomers in each of the following sets should have the greater basicity