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Write a mechanism involving an enolate ion intermediate for the reaction shown in Eq

Chapter 22, Problem 22.3

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QUESTION:

Write a mechanism involving an enolate ion intermediate for the reaction shown in Eq. 22.6. Explain why only the a-hydrogens are replaced by deuterium.

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QUESTION:

Write a mechanism involving an enolate ion intermediate for the reaction shown in Eq. 22.6. Explain why only the a-hydrogens are replaced by deuterium.

ANSWER:

Problem 22.3

Write a mechanism involving an enolate ion intermediate for the reaction shown in Eq. 22.6. Explain why only the a-hydrogens are replaced by deuterium.

                                                             Step by Step Solution

Step 1 of 3

The structure of cyclohexanone is as follows.

 

In this structure,  Hydrogen is most acidic and these are replaced by the deuterium.

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