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Indicate which hydrogen(s) in each of the following molecules (if any) would be
Chapter 22, Problem 22.6(choose chapter or problem)
Indicate which hydrogen(s) in each of the following molecules (if any) would be exchanged for deuterium following base treatment in D2O. (a) (b) (c)
Questions & Answers
QUESTION:
Indicate which hydrogen(s) in each of the following molecules (if any) would be exchanged for deuterium following base treatment in D2O. (a) (b) (c)
ANSWER:Problem 22.6
Indicate which hydrogen(s) in each of the following molecules (if any) would be exchanged for deuterium following base treatment in D2O. (a) (b) (c)
Step by Step Solution
Step 1 of 3
(a)
The carbon atoms that are adjacent to the electron withdrawing groups are called atoms.
The hydrogens which are attached to these carbon atoms are called - hydrogen atoms. These are more acidic and easily replaced by deuterium when treated with deuterium oxide.
The hydrogens are indicated as follows.
These three hydrogen atoms are replaced by deuterium ions. The reaction is as follows.
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