Solution Found!
Explain how you could distinguish between the two compounds in each of the following
Chapter 23, Problem 23.6(choose chapter or problem)
Explain how you could distinguish between the two compounds in each of the following sets using only 13C NMR spectroscopy. (a) 2,2-dimethyl-1-propanamine and 2-methyl-2-butanamine (b) trans-1,2-cyclohexanediamine and trans-1,4-cyclohexanediamine
Questions & Answers
QUESTION:
Explain how you could distinguish between the two compounds in each of the following sets using only 13C NMR spectroscopy. (a) 2,2-dimethyl-1-propanamine and 2-methyl-2-butanamine (b) trans-1,2-cyclohexanediamine and trans-1,4-cyclohexanediamine
ANSWER:Problem 23.6
Explain how you could distinguish between the two compounds in each of the following sets using only 13C NMR spectroscopy. (a) 2,2-dimethyl-1-propanamine and 2-methyl-2-butanamine (b) trans-1,2-cyclohexanediamine and trans-1,4-cyclohexanediamine
Step by Step Solution
Step 1 of 2
(a)
The spectrum of 2,2 -diethyl - 1- propanamine will show five resonance peaks whereas the spectrum of 2- methyl -2 - butanamine will show only four peaks.
The carbons giving different peaks are labeled for both compounds in the adjoining figure.
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