Aniline has a UV spectrum with peaks at lmax 5 230 nm (P 5 8600) and 280 nm (P 5 1430)

Chapter 23, Problem 23.69

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Aniline has a UV spectrum with peaks at lmax 5 230 nm (P 5 8600) and 280 nm (P 5 1430). In the presence of dilute HCl, the spectrum of aniline changes dramatically: lmax 5 203 (P 5 7500) and 254 (P 5 160). This spectrum is nearly identical to the UV spectrum of benzene. Account for the effect of acid on the UV spectrum of aniline.

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