The transition state for enzyme-catalyzed pyrophosphate hydrolysis, deduced from the
Chapter 25, Problem 25.13(choose chapter or problem)
The transition state for enzyme-catalyzed pyrophosphate hydrolysis, deduced from the structure of the enzyme inorganic pyrophosphatase, is shown in Fig. 25.6. (a) Indicate the catalytic role of each numbered featurethat is, how each feature enhances catalysis. (b) If the stereochemistry of the reaction could be determined by isotopic and sulfur substitution of the oxygens, would the result be retention or inversion of configuration at phosphorus?
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