a. Explain why the alkyl halide shown here reacts much more rapidly with guanine than
Chapter 22, Problem 45(choose chapter or problem)
a. Explain why the alkyl halide shown here reacts much more rapidly with guanine than does a primary alkyl halide (such as pentyl chloride). Cl Cl H2N N R N N O + 2 HN + H2N NH2 N R N N N O O + N R N Cl Cl HN NH N N b. The alkyl halide can react with two guanines, each in a different DNA chain, thereby cross-linking the chains. Propose a mechanism for the cross-linking reaction.
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