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Chromatograms of compounds A and B were obtained at the same flow rate with two columns

Quantitative Chemical Analysis | 8th Edition | ISBN: 9781429218153 | Authors: Daniel C. Harris ISBN: 9781429218153 475

Solution for problem 22-28 Chapter 22

Quantitative Chemical Analysis | 8th Edition

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Quantitative Chemical Analysis | 8th Edition | ISBN: 9781429218153 | Authors: Daniel C. Harris

Quantitative Chemical Analysis | 8th Edition

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Problem 22-28

Chromatograms of compounds A and B were obtained at the same flow rate with two columns of equal length. (a) Which column has more theoretical plates? (b) Which column has a larger plate height? (c) Which column gives higher resolution? (d) Which column gives a greater relative retention? (e) Which compound has a higher retention factor? (f) Which compound has a greater partition coefficient? (g) What is the numerical value of the unadjusted relative retention?

Step-by-Step Solution:
Step 1 of 3

Hybridization of Atomic Orbitals (cont.) Double bonds consist of one sigma (σ) and one pi (π) bond Acetylene: C2H2 2 π bonds sp hybridized Carbon H C C H linear 1.20A Carbon sp Energy 1s ( 2s x ) y z 2sp Sp hybridized carbon π ½ π P P π σ sp sp C σ C ½ π π ½ π P P π σ

Step 2 of 3

Chapter 22, Problem 22-28 is Solved
Step 3 of 3

Textbook: Quantitative Chemical Analysis
Edition: 8
Author: Daniel C. Harris
ISBN: 9781429218153

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Chromatograms of compounds A and B were obtained at the same flow rate with two columns