Consider the following statements in reference to SN1,
Chapter 9, Problem 9.43(choose chapter or problem)
Consider the following statements in reference to SN1, SN2, E1, and E2 reactions of haloalkanes. To which mechanism(s), if any, does each statement apply? (a) Involves a carbocation intermediate. (b) Is fi rst order in haloalkane and fi rst order in nucleophile. (c) Involves inversion of confi guration at the site of substitution. (d) Involves retention of confi guration at the site of substitution. (e) Substitution at a stereocenter gives predominantly a racemic product. (f) Is fi rst order in haloalkane and zero order in base. (g) Is fi rst order in haloalkane and fi rst order in base. (h) Is greatly accelerated in protic solvents of increasing polarity. (i) Rearrangements are common. ( j) Order of reactivity of haloalkanes is 3 . 2 . 1. (k) Order of reactivity of haloalkanes is methyl . 1 . 2 . 3.
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