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In what kind of orbitals do the lone-pair electrons on the oxygen of acetone reside

Chapter 1, Problem 1.62

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QUESTION:

In what kind of orbitals do the lone-pair electrons on the oxygen of acetone reside? Arethey in the same plane as the methyl !CH3 groups, or are they perpendicular to themethyl !CH3 groups?

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QUESTION:

In what kind of orbitals do the lone-pair electrons on the oxygen of acetone reside? Arethey in the same plane as the methyl !CH3 groups, or are they perpendicular to themethyl !CH3 groups?

ANSWER:

Key points

Hybridization

Valence bond theory involves the combination of atomic orbitals on each atom in a process called hybridization, and the resulting atomic orbitals are called hybrid orbitals.

  • The  combination of one  atomic orbital and three  atomic orbitals produces four equivalent  hybrid orbitals, each directed toward a corner of a regular tetrahedron at angles of .
  • The combination of one  atomic orbital and two  atomic orbitals produces three equivalent  hybrid orbitals, the axes of which lie in a plane at angles of .
  • The combination of one  atomic orbital and one  atomic orbital produces two equivalent  hybrid orbitals, the axes of which lie at an angle of .
  • Step 1 of 2

    We have to answer the question in what kind of orbitals do the lone-pair electrons on the oxygen of acetone reside? Are they in the same plane as the methyl  groups, or are they perpendicular to the methyl  groups.

    Acetone

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