Following are balanced equations for fluorination of propane to produce a mixture

Chapter 8, Problem 8.18

(choose chapter or problem)

Following are balanced equations for fluorination of propane to produce a mixture of1-fluoropropane and 2-fluoropropane. Assume that each product is formed by a radical chain mechanism.(a) Calculate DH 0 for each reaction.(b) Propose a pair of chain propagation steps for each reaction and calculate DH 0 foreach step.(c) Reasoning from Hammonds postulate, predict the regioselectivity of radical fluori-nation relative to that of radical chlorination and bromination.

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