Each of the following reactions occurs by a radical chain mechanism. (a) Calculate the

Chapter 21, Problem 21.42

(choose chapter or problem)

Each of the following reactions occurs by a radical chain mechanism. (a) Calculate the heat of reaction, DH0, in kJ/mol for each reaction. (Consult Appendix 3for bond dissociation enthalpies.)(b) Write a pair of chain propagation steps for each mechanism and show that the netresult of each pair is the observed reaction.(c) Calculate DH0 for each chain propagation step and show that the sum for each pairof steps is identical with the DH0 value calculated in part (a).

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