E. J. Coreys 1964 total synthesis of a-caryophyllene (essence of cloves) solves a

Chapter 24, Problem 24.39

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E. J. Coreys 1964 total synthesis of a-caryophyllene (essence of cloves) solves a numberof problems of construction of unusual-sized rings. (a) [2 1 2] Reactions are quite common in photochemical reactions. Would this reac-tion be predicted to occur in the ground state?The next steps follow. Basic alumina is a chromatography support that will often act as abase catalyst. (a) [2 1 2] Reactions are quite common in photochemical reactions. Would this reac-tion be predicted to occur in the ground state?The next steps follow. Basic alumina is a chromatography support that will often act as abase catalyst.

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