Solved: A reluctant first-order substrate can be forced to ionize by adding some silver

Chapter 0, Problem 6-29

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A reluctant first-order substrate can be forced to ionize by adding some silver nitrate (one of the few soluble silver salts) to the reaction. Silver ion reacts with the halogen to form a silver halide (a highly exothermic reaction), generating the cation of the alkyl group. Give mechanisms for the following silver-promoted rearrangements.

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