Solved: (a) Draw the three isomers of benzenedicarboxylic acid. (b) The isomers have

Chapter 0, Problem 17-58

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(a) Draw the three isomers of benzenedicarboxylic acid. (b) The isomers have melting points of 210 C, 343 C, and 427 C. Nitration of the isomers at all possible positions was once used to determine their structures. The isomer that melts at 210 C gives two mononitro isomers. The isomer that melts at 343 C gives three mononitro isomers. The isomer that melts at 427 C gives only one mononitro isomer. Show which isomer has which melting point.

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