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Answer: Hydrogen halides (HF, HCl, HBr, HI) are highly
Chapter 4, Problem 4.147(choose chapter or problem)
Hydrogen halides (HF, HCl, HBr, HI) are highly reactive compounds that have many industrial and laboratory uses. (a) In the laboratory, HF and HCl can be generated by reacting CaF2 and NaCl with concentrated sulfuric acid. Write appropriate equations for the reactions. (Hint: These are not redox reactions.) (b) Why is it that HBr and HI cannot be prepared similarly, that is, by reacting NaBr and NaI with concentrated sulfuric acid? (Hint: H2SO4 is a stronger oxidizing agent than both Br2 and I2.) (c) HBr can be prepared by reacting phosphorus tribromide (PBr3) with water. Write an equation for this reaction.
Questions & Answers
QUESTION:
Hydrogen halides (HF, HCl, HBr, HI) are highly reactive compounds that have many industrial and laboratory uses. (a) In the laboratory, HF and HCl can be generated by reacting CaF2 and NaCl with concentrated sulfuric acid. Write appropriate equations for the reactions. (Hint: These are not redox reactions.) (b) Why is it that HBr and HI cannot be prepared similarly, that is, by reacting NaBr and NaI with concentrated sulfuric acid? (Hint: H2SO4 is a stronger oxidizing agent than both Br2 and I2.) (c) HBr can be prepared by reacting phosphorus tribromide (PBr3) with water. Write an equation for this reaction.
ANSWER:Step 1 of 4
(a)
Hydrogen chloride may be prepared in the laboratory by heating sulfuric acid with sodium chloride