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Consider a hypothetical reaction between A, B, and C that is first order in A, zero order in B, and second order in C. (a) Write the rate law for

Chemistry: The Central Science | 14th Edition | ISBN: 9780134414232 | Authors: Theodore E. Brown; H. Eugene LeMay; Bruce E. Bursten; Catherine Murphy; Patrick Woodward; Matthew E. Stoltzfus ISBN: 9780134414232 1274

Solution for problem 14.28 Chapter 14

Chemistry: The Central Science | 14th Edition

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Chemistry: The Central Science | 14th Edition | ISBN: 9780134414232 | Authors: Theodore E. Brown; H. Eugene LeMay; Bruce E. Bursten; Catherine Murphy; Patrick Woodward; Matthew E. Stoltzfus

Chemistry: The Central Science | 14th Edition

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Problem 14.28 Consider a hypothetical reaction between A, B, and C that is first order in A, zero order in B, and second order in C.


(a) Write the rate law for the reaction.


(b) How does the rate change when [A] is doubled and the other reactant concentrations are held constant?


(c) How does the rate change when [B] is tripled and the other reactant concentrations are held constant?


(d) How does the rate change when [C] is tripled and the other reactant concentrations are held constant?


(e) By what factor does the rate change when the concentrations of all three reactants are tripled?


(f) By what factor does the rate change when the concentrations of all three reactants are cut in half?

Step-by-Step Solution:

Step 1 of 5) Equations 18.3 and 18.4 both depend on molecular collisions. (Section 14.5) The concentration of molecules is greater at low altitudes, and so the rates of both reactions are greater at lower altitudes. Because these two effects vary with altitude in opposite directions, the highest rate of O3 formation occurs in a band at an altitude of about 50 km, near the stratopause (Figure 18.1). Overall, roughly 90% of Earth’s ozone is found in the stratosphere. The photodissociation of ozone reverses the reaction that forms it. We thus have a cycle of ozone formation and decomposition, summarized on the next page:Variation in ozone concentration in the atmosphere as a function of altitude.

Step 2 of 2

Chapter 14, Problem 14.28 is Solved
Textbook: Chemistry: The Central Science
Edition: 14
Author: Theodore E. Brown; H. Eugene LeMay; Bruce E. Bursten; Catherine Murphy; Patrick Woodward; Matthew E. Stoltzfus
ISBN: 9780134414232

Chemistry: The Central Science was written by and is associated to the ISBN: 9780134414232. The answer to “Consider a hypothetical reaction between A, B, and C that is first order in A, zero order in B, and second order in C. (a) Write the rate law for the reaction. (b) How does the rate change when [A] is doubled and the other reactant concentrations are held constant? (c) How does the rate change when [B] is tripled and the other reactant concentrations are held constant? (d) How does the rate change when [C] is tripled and the other reactant concentrations are held constant? (e) By what factor does the rate change when the concentrations of all three reactants are tripled? (f) By what factor does the rate change when the concentrations of all three reactants are cut in half?” is broken down into a number of easy to follow steps, and 122 words. This full solution covers the following key subjects: . This expansive textbook survival guide covers 29 chapters, and 2820 solutions. The full step-by-step solution to problem: 14.28 from chapter: 14 was answered by , our top Chemistry solution expert on 10/03/18, 06:29PM. This textbook survival guide was created for the textbook: Chemistry: The Central Science, edition: 14. Since the solution to 14.28 from 14 chapter was answered, more than 240 students have viewed the full step-by-step answer.

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Consider a hypothetical reaction between A, B, and C that is first order in A, zero order in B, and second order in C. (a) Write the rate law for