?Consider the following reaction: \(\mathrm{CH}_{3} \mathrm{Br}(a q)+\mathrm{OH}^{-}(a q) \longrightarrow \mathrm{CH}_{3} \mathrm{OH}(a q)+\ma

Chapter 14, Problem 14.31

(choose chapter or problem)

Consider the following reaction:

\(\mathrm{CH}_{3} \mathrm{Br}(a q)+\mathrm{OH}^{-}(a q) \longrightarrow \mathrm{CH}_{3} \mathrm{OH}(a q)+\mathrm{Br}^{-}(a q)\)

The rate law for this reaction is first order in \(\mathrm{CH}_{3} \mathrm{Br}\) and first order in \(\mathrm{OH}^{-}\). When \(\left[\mathrm{CH}_{3} \mathrm{Br}\right]\) is \(5.0 \times 10^{-3} \mathrm{M}\) and \(\left[\mathrm{OH}^{-}\right]\) is 0.050 M, the reaction rate at 298 K is 0.0432 M/s.

(a) What is the value of the rate constant?

(b) What are the units of the rate constant?

(c) What would happen to the rate if the concentration of \(\mathrm{OH}^{-}\) were tripled?

(d) What would happen to the rate if the concentration of both reactants were tripled?

Text Transcription:

CH_3Br(aq) + OH-(aq) \longrightarrow CH_3OH(aq) + Br-(aq)

CH3Br

OH-

[CH3Br]

5.0 X 10-3 M

[OH- ]

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