Much of our understanding of conformational analysis has

Chapter 26, Problem 26.25

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Much of our understanding of conformational analysis has arisen from studies on the reactions of rigid steroid nuclei. For example, the concept of trans-diaxial ring opening of epoxycyclohexanes was proposed to explain the stereoselective reactions seen with steroidal epoxides. Predict the product when each of the following steroidal epoxides is treated with LiAlH4. (a) H HH O H3C CH3 (c) H O HH H3C CH3 (d) H O HH H3C CH3 (b) H HH O H3C CH3

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