?Complete and balance the following equations, and identify the oxidizing and reducing

Chapter 20, Problem 20.25

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Complete and balance the following equations, and identify the oxidizing and reducing agents:

(a) \(\mathrm{Cr}_{2} \mathrm{O}_{7}^{2-}(a q)+\mathrm{I}^{-}(a q) \longrightarrow \mathrm{Cr}^{3+}(a q)+\mathrm{IO}_{3}^{-}(a q)\) (acidic solution)

(b) \(\mathrm{MnO}_{4}^{-}(a q)+\mathrm{CH}_{3} \mathrm{OH}(a q) \longrightarrow \mathrm{Mn}^{2+}(a q)+$ $\mathrm{HCOOH}(a q)\) (acidic solution)

(c) \(\mathrm{I}_{2}(s)+\mathrm{OCl}^{-}(a q) \longrightarrow \mathrm{IO}_{3}^{-}(a q)+\mathrm{Cl}^{-}(a q)\) (acidic solution)

(d) \(\mathrm{As}_{2} \mathrm{O}_{3}(s)+\mathrm{NO}_{3}^{-}(a q) \longrightarrow \mathrm{H}_{3} \mathrm{AsO}_{4}(a q)+\mathrm{N}_{2} \mathrm{O}_{3}(a q)\) (acidic solution)

(e) \(\mathrm{MnO}_{4}^{-}(a q)+\mathrm{Br}^{-}(a q) \longrightarrow \mathrm{MnO}_{2}(s)+\mathrm{BrO}_{3}^{-}(a q)\) (basic solution)

(f) \(\mathrm{Pb}(\mathrm{OH})_{4}^{2-}(a q)+\mathrm{ClO}^{-}(a q) \longrightarrow \mathrm{PbO}_{2}(s)+\mathrm{Cl}^{-}(a q)\) (basic solution)

Text Transcription:

Cr2O7 2-(aq) + I -(aq) \longrightarrow Cr3+(aq) + IO3 -(aq)

MnO4 -(aq) + CH3OH(aq) \longrightarrow Mn2+(aq) + HCOOH(aq)

I2(s) + OCl -(aq) \longrightarrow IO3 -(aq) + Cl -(aq)

As2O3(s) + NO3 -(aq) \longrightarrow H3AsO4(aq) + N2O3(aq)

MnO4 -(aq) + Br-(aq) \longrightarrow MnO2(s) + BrO3 -(aq)

Pb(OH)4 2-(aq) + ClO-(aq) \longrightarrow PbO2(s) + Cl -(aq)

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