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Atkins' Physical Chemistry | 11th Edition | ISBN: 9780198769866 | Authors: Atkins, Peter; De Paula, Julio; Keeler, James ISBN: 9780198769866 2042

Solution for problem P9B.2 Chapter 9B

Atkins' Physical Chemistry | 11th Edition

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Atkins' Physical Chemistry | 11th Edition | ISBN: 9780198769866 | Authors: Atkins, Peter; De Paula, Julio; Keeler, James

Atkins' Physical Chemistry | 11th Edition

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Problem P9B.2

P9B.2 Imagine a small electron-sensitive probe of volume 1.00 \(\mathrm{pm}^{3}\) inserted into an \(\mathrm{H}_{2}^{+}\) molecule-ion in its ground state. Calculate the probability that it will register the presence of an electron at the following positions: (a) at nucleus A, (b) at nucleus B, (c) half way between A and B, (d) at a point 20 pm along the bond from A and 10 pm perpendicularly. Do the same for the molecule-ion the instant after the electron has been excited into the antibonding LCAO-MO. Take R = \(2.00 a_{0}\).

Text Transcription:

pm^3

H_2^+

2.00 a_0

Step-by-Step Solution:
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Chapter 9B, Problem P9B.2 is Solved
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Textbook: Atkins' Physical Chemistry
Edition: 11
Author: Atkins, Peter; De Paula, Julio; Keeler, James
ISBN: 9780198769866

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