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Atkins' Physical Chemistry | 11th Edition | ISBN: 9780198769866 | Authors: Atkins, Peter; De Paula, Julio; Keeler, James ISBN: 9780198769866 2042

Solution for problem D11C.2 Chapter 11C

Atkins' Physical Chemistry | 11th Edition

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Atkins' Physical Chemistry | 11th Edition | ISBN: 9780198769866 | Authors: Atkins, Peter; De Paula, Julio; Keeler, James

Atkins' Physical Chemistry | 11th Edition

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Problem D11C.2

Describe the effect of vibrational excitation on the rotational constant of a diatomic molecule.

Step-by-Step Solution:
Step 1 of 3

Chapter 15: Chemical Kinetics A. Chemical Kinetics a) Thermodynamics i) Does a reaction take place b) Kinetics i) How fast does a reaction proceed c) Reaction Rate: change in concentration of reactant or product with time (M/s) A B rate= ∆[A] ∆t Δ[A]= change in concentration of A over time period Δt ∆[B ] rate= Δ[B]= change in concentration of B over time ∆t period Δt Because [A] decreases with time, Δ[A] is negative Br (aq)+HCOOH (aq)−→2Br− aq +2H+ (aq)+CO (g) d) 2 2 Br 2 initial ¿ Br2¿ final Average rate= ¿ −∆ B[ 2] =−¿ ∆t i) Instanteaous rate= rate for specific instance in time rate=∝ [r 2] rate=k[Br 2 k= rate =rateconstant [Br 2 −3 −1 ¿3.50∗10 s ii) 2H 2 2(aq)−→2H O 2 (l+O 2(g) PV=nRT n P= RT=[O ]2 RT V [ 2 1 P Measure

Step 2 of 3

Chapter 11C, Problem D11C.2 is Solved
Step 3 of 3

Textbook: Atkins' Physical Chemistry
Edition: 11
Author: Atkins, Peter; De Paula, Julio; Keeler, James
ISBN: 9780198769866

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