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Get Full Access to Atkins' Physical Chemistry - 11 Edition - Chapter 13a - Problem P13a.3
Get Full Access to Atkins' Physical Chemistry - 11 Edition - Chapter 13a - Problem P13a.3

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ISBN: 9780198769866 2042

## Solution for problem P13A.3 Chapter 13A

Atkins' Physical Chemistry | 11th Edition

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Atkins' Physical Chemistry | 11th Edition

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Problem P13A.3

Use mathematical software to evaluate W for N=20 for at least ten distributions over a uniform ladder of energy levels with separation $$\varepsilon$$, ensuring that the total energy is constant at $$10 \varepsilon$$. Identify the configuration of greatest weight, expressing the temperature as a multiple of $$\varepsilon$$, and compare it to the distribution predicted by the Boltzmann expression. Explore what happens as the value of the total energy is changed.

Text Transcription:

varepsilon

10 varepsilon

Step-by-Step Solution:
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4.16-4.20 Monday,April16,2018 12:18PM Whichacidwouldyouchoosetocreateabuffer withpH=7.35Ifyouhave500.0mLofa0.10M solutionoftheacid,whatmassofthe correspondingsodiumsaltoftheconjugatebase doyouneedtomakethebuffer chlorousacid(HClO2) pKa=1.9 formicacid(HCHO2) pKa=3.74 nitrousacid(HNO2) pKa=3.34 hypochlorousacid(HClO)pKa=7.54

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