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Textbooks / Chemistry / Atkins' Physical Chemistry 11 / Chapter 13A / Problem P13A.3

Atkins' Physical Chemistry | 11th Edition | ISBN: 9780198769866 | Authors: Atkins, Peter; De Paula, Julio; Keeler, James ISBN: 9780198769866 2042

Solution for problem P13A.3 Chapter 13A

Atkins' Physical Chemistry | 11th Edition

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Atkins' Physical Chemistry | 11th Edition | ISBN: 9780198769866 | Authors: Atkins, Peter; De Paula, Julio; Keeler, James

Atkins' Physical Chemistry | 11th Edition

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Problem P13A.3

Use mathematical software to evaluate W for N=20 for at least ten distributions over a uniform ladder of energy levels with separation \(\varepsilon\), ensuring that the total energy is constant at \(10 \varepsilon\). Identify the configuration of greatest weight, expressing the temperature as a multiple of \(\varepsilon\), and compare it to the distribution predicted by the Boltzmann expression. Explore what happens as the value of the total energy is changed.

Text Transcription:

varepsilon

10 varepsilon

Step-by-Step Solution:
Step 1 of 3

4.16-4.20 Monday,April16,2018 12:18PM Whichacidwouldyouchoosetocreateabuffer withpH=7.35Ifyouhave500.0mLofa0.10M solutionoftheacid,whatmassofthe correspondingsodiumsaltoftheconjugatebase doyouneedtomakethebuffer chlorousacid(HClO2) pKa=1.9 formicacid(HCHO2) pKa=3.74 nitrousacid(HNO2) pKa=3.34 hypochlorousacid(HClO)pKa=7.54

Step 2 of 3

Chapter 13A, Problem P13A.3 is Solved
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Textbook: Atkins' Physical Chemistry
Edition: 11
Author: Atkins, Peter; De Paula, Julio; Keeler, James
ISBN: 9780198769866

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