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Atkins' Physical Chemistry | 11th Edition | ISBN: 9780198769866 | Authors: Atkins, Peter; De Paula, Julio; Keeler, James ISBN: 9780198769866 2042

Solution for problem E15B.8(a) Chapter 15B

Atkins' Physical Chemistry | 11th Edition

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Atkins' Physical Chemistry | 11th Edition | ISBN: 9780198769866 | Authors: Atkins, Peter; De Paula, Julio; Keeler, James

Atkins' Physical Chemistry | 11th Edition

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Problem E15B.8(a)

In an X-ray investigation, the following structure factors were determined (with \(F_{-h 00}=F_{h 00}\) ):

\(\begin{array}{rrrrrrrrrrr}h & 0 & 1 & 2 & 3 & 4 & 5 & 6 & 7 & 8 & 9 \\ F_{h 00} & 10 & -10 & 8 & -8 & 6 & -6 & 4 & -4 & 2 & -2\end{array}\)

Construct the electron density along the corresponding direction.

Text Transcription:

F_-h 00=F_h 00

F_h 00

Step-by-Step Solution:
Step 1 of 3

Organic Chemistry II Spring 2018 Dr. Paul Johnson Lecture 1:Sections 13.7,13.10 ● Review from the first semester ● Sodium hydride (NaH) and Lithium diisopropyl amide (LDA) are strong bases that abstract protons from very weak acids. They are not nucleophiles ○ ● PCC oxidizes primary alcohols to aldehydes ○ ● H2​CrO4​and CrO​ 3​ater/acetone (Jones reagent) oxidize primary alcohols and aldehydes to carboxylic acids ○ ● Phosphorus tribromide converts primary and secondary alcohols to alkyl bromides ○ ● Elimination reactions that produce alkenes ○ ● Relative acidity review +​ ● Strong acids: H​2​O​4​H3​O​ ,3​ P4​ ,HI,HBr,HCl pKa<0 ● These protons can be easily abstracted by HO​ - ○ ○ Example ○ ● These protons cannot be abstracted by hydroxide ion. A stronger base must be used ○ ROH ● These protons can be abstracted by a base ○ ● Solvents and leaving group review ● Solvents ○ Protic nucleophilic solvents:ROH such as methanol, ethanol, etc ○ Protic nucleophilic solvents that can potentially participate in SN1 solvolysis: ethanoic acid (CH3​COOH) = HOAc, H​2​ ○ Aprotic polar inert solvents:DMF, DMSO ■ These are typical solvents for SN2 reactions with category II nucleophiles ○ Aprotic, nonpolar solvents: dichloromethane CH​

Step 2 of 3

Chapter 15B, Problem E15B.8(a) is Solved
Step 3 of 3

Textbook: Atkins' Physical Chemistry
Edition: 11
Author: Atkins, Peter; De Paula, Julio; Keeler, James
ISBN: 9780198769866

This textbook survival guide was created for the textbook: Atkins' Physical Chemistry, edition: 11. Since the solution to E15B.8(a) from 15B chapter was answered, more than 201 students have viewed the full step-by-step answer. Atkins' Physical Chemistry was written by Aimee Notetaker and is associated to the ISBN: 9780198769866. The full step-by-step solution to problem: E15B.8(a) from chapter: 15B was answered by Aimee Notetaker, our top Chemistry solution expert on 04/25/22, 03:45PM. The answer to “?In an X-ray investigation, the following structure factors were determined (with \(F_{-h 00}=F_{h 00}\) ):\(\begin{array}{rrrrrrrrrrr}h & 0 & 1 & 2 & 3 & 4 & 5 & 6 & 7 & 8 & 9 \\ F_{h 00} & 10 & -10 & 8 & -8 & 6 & -6 & 4 & -4 & 2 & -2\end{array}\)Construct the electron density along the corresponding direction.Text Transcription:F_-h 00=F_h 00F_h 00” is broken down into a number of easy to follow steps, and 69 words. This full solution covers the following key subjects: . This expansive textbook survival guide covers 327 chapters, and 1120 solutions.

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