Answer: Consider the following mechanism for the

Chapter 13, Problem 13.66

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Consider the following mechanism for the enzymecatalyzed reaction: (fast equilibrium) ES (slow) k2 E P ESk1 k 1 1 ES 1 Derive an expression for the rate law of the reaction in terms of the concentrations of E and S. (Hint: To solve for [ES], make use of the fact that, at equilibrium, the rate of forward reaction is equal to the rate of the reverse reaction.)

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