Liquid ammonia autoionizes like water: where (am)

Chapter 18, Problem 18.160

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Liquid ammonia autoionizes like water: where (am) represents solvation by NH3. (a) Write the ion- product constant expression, Kam. (b) What are the strongest acid and base that can exist in NH3(l)? (c) HNO3 and HCOOH are leveled in NH3(l). Explain with equations. (d) At the boiling point (?33C), Kam ? 5.1?10?27. Calculate [NH4 ] at this temperature. (e) Pure sulfuric acid also autoionizes. Write the ion-product constant expression, Ksulf, and find the concentration of the conjugate base at 20C (Ksulf ? 2.? 0?4 at 20C). 18

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