A galvanic cell is constructed as follows. One halfcell consists of a platinum wire immersed in a solution containing 1.0 M Sn21 and 1.0 M Sn41; the other half-cell has a thallium rod immersed in a solution of 1.0 M Tl1. (a) Write the half-cell reactions and the overall reaction. (b) What is the equilibrium constant at 25C? (c) What is the cell voltage if the T11 concentration is increased tenfold? (E Tl1/Tl 5 20.34 V.)
Problem 18.109A galvanic cell is constructed as follows. One half cell consists of a platinum wire immersedin a solution containing 1.0 M Sn 2+ and 1.0 M Sn ; the other half-cell has a thallium rodimmersed in a solution of 1.0 M Tl . (a) Write the half-cell reactions and the overallreaction. (b) What is the equilibrium constant at 25°C (c) What is the cell voltage if theT1 concentration is increased ten fold (E° = 0.34 V.) Tl+/Tl Step by step solutionStep 1 of 3(a)The two half cell reactions are as follows.The overall balanced reaction isThe standard cell potential is as follows.Therefore, The standard cell potential is +0.47V._______________________________________________________________________