The solubility of Ag(I) in aqueous solutions containing

Chapter 19, Problem 19.155

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The solubility of Ag(I) in aqueous solutions containing different concentrations of Cl is based on the following equilibria: When solid AgCl is shaken with a solution containing Cl, Ag(I) is present as both Ag? and AgCl2 . The solubility of AgCl is the sum of the concentrations of Ag? and AgCl2 . (a) Show that [Ag?] in solution is given by ] and that [AgCl2 ] in solution is given by (b) Find the [Cl] at which [Ag?] ? [AgCl2 ]. (c) Explain the shape of a plot of AgCl solubility vs. [Cl]. (d) Find the solubility of AgCl at the [Cl] of part (b), which is the minimum solubility of AgCl in the presence of Cl. 19.156

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