The solubility of Ag(I) in aqueous solutions containing
Chapter 19, Problem 19.155(choose chapter or problem)
The solubility of Ag(I) in aqueous solutions containing different concentrations of Cl is based on the following equilibria: When solid AgCl is shaken with a solution containing Cl, Ag(I) is present as both Ag? and AgCl2 . The solubility of AgCl is the sum of the concentrations of Ag? and AgCl2 . (a) Show that [Ag?] in solution is given by ] and that [AgCl2 ] in solution is given by (b) Find the [Cl] at which [Ag?] ? [AgCl2 ]. (c) Explain the shape of a plot of AgCl solubility vs. [Cl]. (d) Find the solubility of AgCl at the [Cl] of part (b), which is the minimum solubility of AgCl in the presence of Cl. 19.156
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