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Ammonia appears in Table 1-5 both as an acid and as a

Chapter 1, Problem 14P

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QUESTION:

Ammonia appears in Table 1-5 both as an acid and as a conjugate base.

(a) Explain how ammonia can act as both an acid and a base. Which of these roles does it commonly fill in aqueous solutions?

(b) Show how water can serve as both an acid and a base.

(c) Calculate \(K_{a} \text { and } p K_{a}\) for the hydronium ion,

      \(\mathrm{H}_{3} \mathrm{O}^{+}\).

(d) Show how methanol \(\left(\mathrm{CH}_{3} \mathrm{OH}\right)\) can serve as both an acid and a base. Write an equation for the reaction of methanol with sulfuric acid.

Equation Transcription:

Text Transcription:

Ka and pKa

H3O+

(CH3OH)

Questions & Answers

QUESTION:

Ammonia appears in Table 1-5 both as an acid and as a conjugate base.

(a) Explain how ammonia can act as both an acid and a base. Which of these roles does it commonly fill in aqueous solutions?

(b) Show how water can serve as both an acid and a base.

(c) Calculate \(K_{a} \text { and } p K_{a}\) for the hydronium ion,

      \(\mathrm{H}_{3} \mathrm{O}^{+}\).

(d) Show how methanol \(\left(\mathrm{CH}_{3} \mathrm{OH}\right)\) can serve as both an acid and a base. Write an equation for the reaction of methanol with sulfuric acid.

Equation Transcription:

Text Transcription:

Ka and pKa

H3O+

(CH3OH)

ANSWER:

Answer :

Step 1:

An acid is any species that can donate a proton .

Ammonia has a proton bonded to nitrogen ,so ammonia can be a weak acid .A base is a proton acceptor ,that is it must have a pair of electrons to share with a proton .

Any atom with an unshared electron pair can be a base ,the nitrogen in ammonia has an unshared electron pair so ammonia is basic .

In water ammonia is too weak acid to give up its proton,it acts as a base and pulls a proton from water to a small extent.

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