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Predict the major products of the following reactions,
Chapter 3, Problem 41SP(choose chapter or problem)
Problem 41SP
Predict the major products of the following reactions, including stereochemistry where appropriate.
(a) ( R)-butan-2-ol + TsCl in pyridine
(b) (S)-2-butyl tosylate + NaBr
(c) cyclooctanol + CrO3/H2SO4
(d) cyclopentylmethanol + CrO3 . pyridine. HCl
(e) cyclopentylmethanol + Na2Cr2O7/H2SO4
(f) cyclopentanol + HCl/ZnCl2
(g) n-butanol + HBr
(h) cyclooctylmethanol + CH3CH2MgBr
(i) potassium tert-butoxide + methyl iodide
(j) sodium methoxide + tert-butyl iodide
(k) cyclopentanol + H2SO4/heat
(l) product from (k) + OsO4/H2O2, then HIO4
(m) sodium ethoxide + 1-bromobutane
(n) sodium ethoxide + 2-methyl-2-bromobutane
(o) octan-1-ol + DMSO + oxalyl chloride
(p) 4-cyclopentylhexan-1-ol + DMP reagent
Questions & Answers
QUESTION:
Problem 41SP
Predict the major products of the following reactions, including stereochemistry where appropriate.
(a) ( R)-butan-2-ol + TsCl in pyridine
(b) (S)-2-butyl tosylate + NaBr
(c) cyclooctanol + CrO3/H2SO4
(d) cyclopentylmethanol + CrO3 . pyridine. HCl
(e) cyclopentylmethanol + Na2Cr2O7/H2SO4
(f) cyclopentanol + HCl/ZnCl2
(g) n-butanol + HBr
(h) cyclooctylmethanol + CH3CH2MgBr
(i) potassium tert-butoxide + methyl iodide
(j) sodium methoxide + tert-butyl iodide
(k) cyclopentanol + H2SO4/heat
(l) product from (k) + OsO4/H2O2, then HIO4
(m) sodium ethoxide + 1-bromobutane
(n) sodium ethoxide + 2-methyl-2-bromobutane
(o) octan-1-ol + DMSO + oxalyl chloride
(p) 4-cyclopentylhexan-1-ol + DMP reagent
ANSWER: