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Under certain conditions, the bromination of cyclohexene

Chapter 5, Problem 12P

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QUESTION:

Under certain conditions, the bromination of cyclohexene follows an unusual rate law:

What is the kinetic order with respect to cyclohexene?What is the kinetic order with respect to bromine?What is the overall kinetic order?

Equation Transcription:

Text Transcription:

H H +Br_2 H Br Br H rate=k_r[cyclohexene] [ Br_2]^2

Questions & Answers

QUESTION:

Under certain conditions, the bromination of cyclohexene follows an unusual rate law:

What is the kinetic order with respect to cyclohexene?What is the kinetic order with respect to bromine?What is the overall kinetic order?

Equation Transcription:

Text Transcription:

H H +Br_2 H Br Br H rate=k_r[cyclohexene] [ Br_2]^2

ANSWER:

Answer :

(a) The kinetic order with respect to cyclohexene is first order .

The exponent of [cyclohexene] in the rate law =1.

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