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(a) Draw a reaction-energy diagram for the following

Organic Chemistry | 8th Edition | ISBN: 9780321768414 | Authors: L.G. Wade Jr ISBN: 9780321768414 33

Solution for problem 15P Chapter 4

Organic Chemistry | 8th Edition

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Organic Chemistry | 8th Edition | ISBN: 9780321768414 | Authors: L.G. Wade Jr

Organic Chemistry | 8th Edition

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Problem 15P

(a) Draw a reaction-energy diagram for the following reaction:

The activation energy is 4 kJ/mol (1 kcal/mol), and the overall  for the reaction is

-109 kJ/mol (-26 kcal/mol).

(b) Give the equation for the reverse reaction.

(c) What is the activation energy for the reverse reaction?

Step-by-Step Solution:

Solution 15P :

Step 1:

(a) Draw a reaction-energy diagram for the following reaction:

The activation energy is 4 kJ/mol (1 kcal/mol), and the overall Ho for the reaction is

-109 kJ/mol (-26 kcal/mol).

Reaction energy diagram is the graph of reaction progress versus energy. The vertical axis represents the overall energy of the reactants and the horizontal axis represents the reaction progress.

The above reaction is a propagation reaction, as we see a radical(•CH3) in the reactant has reacted to form a free radical in the product(Cl•) . The reaction energy diagram for the above reaction is as shown below:

Step 2:

(b) Give the equation for the reverse reaction :

The reverse reaction for the above equation is :

        CH3Cl  +  Cl •   →  Cl2  +  CH3 •

Step 3 of 3

Chapter 4, Problem 15P is Solved
Textbook: Organic Chemistry
Edition: 8
Author: L.G. Wade Jr
ISBN: 9780321768414

Since the solution to 15P from 4 chapter was answered, more than 558 students have viewed the full step-by-step answer. The full step-by-step solution to problem: 15P from chapter: 4 was answered by , our top Chemistry solution expert on 05/06/17, 06:41PM. This textbook survival guide was created for the textbook: Organic Chemistry, edition: 8. The answer to “(a) Draw a reaction-energy diagram for the following reaction: The activation energy is 4 kJ/mol (1 kcal/mol), and the overall for the reaction is-109 kJ/mol (-26 kcal/mol).(b) Give the equation for the reverse reaction.(c) What is the activation energy for the reverse reaction?” is broken down into a number of easy to follow steps, and 43 words. Organic Chemistry was written by and is associated to the ISBN: 9780321768414. This full solution covers the following key subjects: reaction, mol, Energy, Activation, kcal. This expansive textbook survival guide covers 25 chapters, and 1336 solutions.

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