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Allylic halides have the structure (a) Show how the

Organic Chemistry | 8th Edition | ISBN: 9780321768414 | Authors: L.G. Wade Jr ISBN: 9780321768414 33

Solution for problem 52SP Chapter 6

Organic Chemistry | 8th Edition

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Organic Chemistry | 8th Edition | ISBN: 9780321768414 | Authors: L.G. Wade Jr

Organic Chemistry | 8th Edition

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Problem 52SP

Allylic halides have the structure

(a) Show how the first-order ionization of an allylic halide leads to a resonance-stabilized cation.

(b) Draw the resonance structures of the allylic cations formed by ionization of the following halides.

(c) Show the products expected from SN1 solvolysis of these halides in ethanol.

Step-by-Step Solution:
Step 1 of 3

Step-1

The structure of allylic halide is,

(a) The  first-order ionization of an allylic halide and the resonance stabilization is given below-

In this 1st order ionization process, the halide group (X), from the allyl halide has been released as X- ion and forms a carbocation. This carbocation has two resonance structures.

Step-2

Resonance structures of the allylic cations :-

 

Step-3

CH3-CH2OH

Step 2 of 3

Chapter 6, Problem 52SP is Solved
Step 3 of 3

Textbook: Organic Chemistry
Edition: 8
Author: L.G. Wade Jr
ISBN: 9780321768414

Since the solution to 52SP from 6 chapter was answered, more than 948 students have viewed the full step-by-step answer. This full solution covers the following key subjects: allylic, halides, resonance, ionization, ethanol. This expansive textbook survival guide covers 25 chapters, and 1336 solutions. This textbook survival guide was created for the textbook: Organic Chemistry, edition: 8. The answer to “Allylic halides have the structure (a) Show how the first-order ionization of an allylic halide leads to a resonance-stabilized cation.(b) Draw the resonance structures of the allylic cations formed by ionization of the following halides.(c) Show the products expected from SN1 solvolysis of these halides in ethanol.” is broken down into a number of easy to follow steps, and 47 words. Organic Chemistry was written by and is associated to the ISBN: 9780321768414. The full step-by-step solution to problem: 52SP from chapter: 6 was answered by , our top Chemistry solution expert on 05/06/17, 06:41PM.

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