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Allylic halides have the structure (a) Show how the

Organic Chemistry | 8th Edition | ISBN: 9780321768414 | Authors: L.G. Wade Jr ISBN: 9780321768414 33

Solution for problem 52SP Chapter 6

Organic Chemistry | 8th Edition

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Organic Chemistry | 8th Edition | ISBN: 9780321768414 | Authors: L.G. Wade Jr

Organic Chemistry | 8th Edition

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Problem 52SP

Allylic halides have the structure

(a) Show how the first-order ionization of an allylic halide leads to a resonance-stabilized cation.

(b) Draw the resonance structures of the allylic cations formed by ionization of the following halides.

(c) Show the products expected from \(S_{N} 1\) solvolysis of these halides in ethanol

Equation Transcription:

Text Transcription:

C=C-C-X

S_N1

Br

CH2Br

Br

Br

Step-by-Step Solution:

Solution:

Step 1

The structure of allylic halide is,

(a) The  first-order ionization of an allylic halide and the resonance stabilization is given below-

In this 1st order ionization process, the halide group (X), from the allyl halide has been released as X- ion and forms a carbocation. This carbocation has two resonance structures.

Step 2 of 3

Chapter 6, Problem 52SP is Solved
Step 3 of 3

Textbook: Organic Chemistry
Edition: 8
Author: L.G. Wade Jr
ISBN: 9780321768414

Since the solution to 52SP from 6 chapter was answered, more than 1444 students have viewed the full step-by-step answer. This full solution covers the following key subjects: allylic, halides, resonance, ionization, ethanol. This expansive textbook survival guide covers 25 chapters, and 1336 solutions. This textbook survival guide was created for the textbook: Organic Chemistry, edition: 8. The answer to “?Allylic halides have the structure (a) Show how the first-order ionization of an allylic halide leads to a resonance-stabilized cation.(b) Draw the resonance structures of the allylic cations formed by ionization of the following halides. (c) Show the products expected from \(S_{N} 1\) solvolysis of these halides in ethanol Equation Transcription:Text Transcription:C=C-C-XS_N1BrCH2BrBrBr” is broken down into a number of easy to follow steps, and 52 words. Organic Chemistry was written by and is associated to the ISBN: 9780321768414. The full step-by-step solution to problem: 52SP from chapter: 6 was answered by , our top Chemistry solution expert on 05/06/17, 06:41PM.

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