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Shapes & Forces: How Molecule Structure Affects Bonds

Chapter 12, Problem 65P

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QUESTION:

What kinds of intermolecular forces are present in each substance?

(a) \(\mathrm{NCl}_{3}\) (trigonal pyramidal)

(b) \(\mathrm{NH}_{3}\) (trigonal pyramidal)

(c) \(\mathrm{SiH}_{4}\) (tetrahedral)

(d) \(\mathrm{CCl}_{4}\) (tetrahedral)

Questions & Answers

QUESTION:

What kinds of intermolecular forces are present in each substance?

(a) \(\mathrm{NCl}_{3}\) (trigonal pyramidal)

(b) \(\mathrm{NH}_{3}\) (trigonal pyramidal)

(c) \(\mathrm{SiH}_{4}\) (tetrahedral)

(d) \(\mathrm{CCl}_{4}\) (tetrahedral)

ANSWER:

Step 1 of 2

(a) Nitrogen trichloride, or \(\mathrm{NCl}_{3}\), has a trigonal pyramidal shape. It exhibits two types of intermolecular forces: London dispersion forces and dipole-dipole forces.

London dispersion forces are temporary attractive forces that exist between all molecules, while dipole-dipole forces exist between molecules with a permanent dipole, which \(\mathrm{NCl}_{3}\) has due to its shape and polar bonds.

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Shapes & Forces: How Molecule Structure Affects Bonds
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Unveil the correlation between molecular shapes and their respective intermolecular forces. Delve into the specifics of nitrogen trichloride, ammonia, silane, and carbon tetrachloride, highlighting their unique force interactions based on polarity.


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