Catalysis (Section)The oxidation of SO2 to SO3 is

Chapter 6, Problem 85E

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Problem  85E

Catalysis (Section)

The oxidation of SO2 to SO3 is accelerated by NO2. The reaction proceeds according to:

NO2(g) + SO2(g)→ NO(g) + SO3(g)

2 NO(g) + O2(g)→2 NO2(g)

(a) Show that, with appropriate coefficients, the two reactions can be summed to give the overall oxidation of SO2 by O2 to give SO3. (b) Do we consider NO2 a catalyst or an intermediate in this reaction? (c) Is this an example of homogeneous catalysis or heterogeneous catalysis?

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